nodeSelector is the node selector applied to the relevant kind of pods It specifies a map of key-value pairs: for the pod to be eligible to run on a node, the node must have each of the indicated key-value pairs as labels (it can have additional labels as well). See https://kubernetes.io/docs/concepts/configuration/assign-pod-node/#nodeselector
tolerations is a list of tolerations applied to the relevant kind of pods See https://kubernetes.io/docs/concepts/configuration/taint-and-toleration/ for more info. These are additional tolerations other than default ones.
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NodePlacement describes node scheduling configuration.
V1NodePlacement